High resolution threshold photoelectron spectrum and autoionization processes of S2 up to 15.0 eV

نویسندگان

چکیده

VUV photoionization dynamics of the S2 molecule were re-investigated from threshold up to 15.0 eV, using synchrotron radiation coupled with double imaging photoelectron/photoion coincidence featuring high resolution capabilities. We measured first photoelectron spectrum achieving higher than previous literature derive accurate spectroscopic constants for a few electronic states cation including X2ΠΩ,g ground state and a4Πu, b4Σg–, B2Σg– states. also recorded total ion yield photon energy eV which, combined spectrum, led assignment various autoionizing Rydberg series.

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ژورنال

عنوان ژورنال: Journal of Molecular Spectroscopy

سال: 2021

ISSN: ['0022-2852', '1096-083X']

DOI: https://doi.org/10.1016/j.jms.2021.111533